Parallel-disk and cone-and-plate viscometry of a viscoplastic hydrogel with apparent wall slip

TL;DR

This study demonstrates that parallel-disk viscometry effectively characterizes the viscoplastic and wall slip behavior of hydrogels, providing accurate parameters for their rheological modeling and potential for improved hydrogel design.

Contribution

It introduces a methodology using parallel-disk viscometry to unambiguously determine viscoplastic parameters and wall slip behavior of hydrogels, overcoming limitations of traditional cone-and-plate methods.

Findings

Parallel-disk viscometry accurately measures yield stress and wall slip.

Gap-dependent data enables detailed rheological parameter determination.

Methodology shows excellent agreement between calculated and experimental flow data.

Abstract

Hydrogels are widely used in myriad applications including those in the biomedical and personal care fields. It is generally the rheology, i.e., the flow and deformation properties, of hydrogels that define their functionalities. However, the ubiquitous viscoplasticity and associated wall slip behavior of hydrogels handicap the accurate characterization of their rheological material functions. Here parallel-disk and cone-and-plate viscometers were used to characterize the shear viscosity and wall slip behavior of a crosslinked poly(acrylic acid), PAA, hydrogel (carbomer, specifically Carbopol). It is demonstrated that parallel-disk viscometry, i.e., the steady torsional flow in between two parallel disks, but not the cone-and-plate flow can be used to determine the yield stress and other parameters of viscoplastic constitutive equations and wall slip behavior unambiguously. Gap-dependent data from parallel-disk viscometry can then be used to characterize the other parameters of the shear viscosity and wall slip behavior of the hydrogel. The accuracies of the parameters of wall slip and Herschel-Bulkley type viscoplastic constitutive equation in representing the flow and deformation behavior of the hydrogel were tested via the comparisons of the calculated and experimentally determined velocity distributions and torques. The excellent agreements found reflect the accuracies of the parameters of shear viscosity and wall slip and indicate that the methodologies demonstrated here provide the means necessary to understand in detail the steady flow and deformation behavior of hydrogels. Such a detailed understanding of the viscoplastic nature and wall slip behavior of hydrogels can then be used to design and develop novel hydrogels with a wider range of applications in the medical and other industrial areas, and for finding optimum conditions for their processing and manufacturing.