Discovering of the L ligand impact on luminescence enhancement of Eu(Dibenzoylmethane)3.Lx complexes employing transient absorption spectroscopy

TL;DR

This study investigates how changing the auxiliary ligand in Eu(Dibenzoylmethane)3 complexes affects luminescence enhancement, revealing complex interactions between nonradiative relaxation, energy transfer, and triplet state population through transient absorption spectroscopy.

Contribution

It provides new insights into the role of auxiliary ligands in modulating luminescence and excited state dynamics in europium complexes using transient absorption spectroscopy.

Findings

Auxiliary ligand reduces nonradiative relaxation rate.

Energy transfer efficiency correlates with triplet state population.

Ligand exchange acts as a switch for intersystem crossing.

Abstract

The effect of luminescent enhancement under exchange of the auxiliary ligand in Europium(III) tris(1,3-diphenyl-1,3-propanedionato) monohydrate was investigated by steady-state and time-resolved transient absorption spectroscopy. The excited state relaxation dynamics of this complex was analyzed through a comparison of the experimental data obtained for several model compounds, namely Eu(DBM)3.NH3, Eu(DBM)3.EDA, Eu(DBM)3.Phen, Al(DBM)3 and dibenzoyl methane (DBM) in various solutions and polymer matrices. The results show there is no linear relationship between enhancement of the emission quantum yield and the luminescent lifetime, which suggests that the auxiliary ligand reduces the rate of nonradiative relaxation of the lanthanide ion, but also affects the excited state energy transfer from ligand to metal ion. Transient absorption data shows a clear correlation between the efficiency of the energy transfer and the degree of triplet state population expressed by an amplification of the signal for its excited state absorption band on going from Eu(DBM)3.H2O to the Eu(DBM).L complex. The results show that this auxiliary ligand exchange acts as a switch turning the intersystem crossing on or off as a competitive pathway for excited state relaxation of the europium(III) complexes.