The role of neutral hydrogen in setting the abundances of molecular species in the Milky Way's diffuse interstellar medium. II. Comparison between observations and theoretical models

TL;DR

This study compares observations of neutral hydrogen and HCO$^+$ in the diffuse interstellar medium with theoretical models, revealing that non-equilibrium processes may be necessary to explain certain molecular abundances.

Contribution

It provides a detailed comparison between observational data and PDR and multi-phase ISM models, highlighting the importance of non-equilibrium chemistry in the diffuse ISM.

Findings

Structures with low T_s are consistent with diffuse molecular ISM models.

High T_s structures suggest environments near star formation.

Observed HCO$^+$ column densities often exceed model predictions, indicating non-equilibrium processes.

Abstract

We compare observations of HI from the Very Large Array (VLA) and the Arecibo Observatory and observations of HCO$^+$ from the Atacama Large Millimeter/submillimeter Array (ALMA) and the Northern Extended Millimeter Array (NOEMA) in the diffuse ($A_V\lesssim1$) interstellar medium (ISM) to predictions from a photodissociation region (PDR) chemical model and multi-phase ISM simulations. Using a coarse grid of PDR models, we estimate the density, FUV radiation field, and cosmic ray ionization rate (CRIR) for each structure identified in HCO$^+$ and HI absorption. These structures fall into two categories. Structures with $T_s<40~\mathrm{K}$, mostly with $N(\mathrm{HCO^+})\lesssim10^{12}~\mathrm{cm^{-2}}$, are consistent with modest density, FUV radiation field, and CRIR models, typical of the diffuse molecular ISM. Structures with spin temperature $T_s>40~\mathrm{K}$, mostly with $N(\mathrm{HCO^+})\gtrsim10^{12}~\mathrm{cm^{-2}}$, are consistent with high density, FUV radiation field, and CRIR models, characteristic of environments close to massive star formation. The latter are also found in directions with a significant fraction of thermally unstable HI. In at least one case, we rule out the PDR model parameters, suggesting that alternative mechanisms (e.g., non-equilibrium processes like turbulent dissipation and/or shocks) are required to explain the observed HCO$^+$ in this direction. Similarly, while our observations and simulations of the turbulent, multi-phase ISM agree that HCO$^+$ formation occurs along sightlines with $N(\mathrm{HI})\gtrsim10^{21}~\mathrm{cm^{-2}}$, the simulated data fail to explain HCO$^+$ column densities $\gtrsim\rm{few}\times10^{12}~\mathrm{cm^{-2}}$. Since a majority of our sightlines with HCO$^+$ had such high column densities, this likely indicates that non-equilibrium chemistry is important for these lines of sight.