Unusual Dynamical Properties of Disordered Polaritons in Micocavities

TL;DR

This paper develops an analytical framework to understand how energetic disorder affects the spectral and transport properties of disordered polaritons in microcavities, revealing novel dynamical regimes and the role of dark states.

Contribution

The authors introduce an exact Green's function solution to the Fano-Anderson model for disordered microcavities, deriving scaling laws and elucidating the impact of dark states on transport.

Findings

Identification of an exceptional point leading to different dynamical regimes.

Exact partitioning of the density of states into cavity, bright, and dark components.

Proportionality between relaxation and transport rates related to the local density of states.

Abstract

The strong light-matter interaction in microcavities gives rise to intriguing phenomena, such as cavity-mediated transport that can potentially overcome the Anderson localization. Yet, an accurate theoretical treatment is challenging as the matter (e.g.,molecules) are subject to large energetic disorder. In this article, we develop the Green's function solution to the Fano-Anderson model and use the exact analytical solution to quantify the effects of energetic disorder on the spectral and transport properties in microcavities. Starting from microscopic equation of motions, we derive an effective non-Hermitian Hamiltonian and predict a set of scaling laws: (i) The complex eigen-energies of the effective Hamiltonian exhibit an exceptional point, which leads to underdamped coherent dynamics in the weak disorder regime, where the decay rate increases with disorder, and overdamped incoherent dynamics in the strong disorder regime, where the slow decay rate decreases with disorder. (ii) The total density of states of disordered ensembles can be exactly partitioned into the cavity, bright-state and dark-state local density of states, which are determined by the complex eigen solutions and can be measured via spectroscopy. (iii) The cavity-mediated relaxation and transport dynamics are intimately related such that the energy-resolved relaxation and transport rates are proportional to the cavity local density of states. The ratio of the disorder averaged relaxation and transport rates equals the molecule number, which can be interpreted as a result of a quantum random walk. (iv) A turnover in the rates as a function of disorder or molecule density can be explained in terms of the overlap of the disorder distribution function and the cavity local density of states. These findings reveal the significant impact of the dark states on the transport properties of disordered ensembles in cavities.