Sulfur gas-phase abundance in dense cores

TL;DR

This study investigates sulfur abundance in dense star-forming cores, revealing that atomic sulfur is not depleted in early stages but becomes depleted in evolved cores, with implications for understanding sulfur chemistry.

Contribution

It provides the first direct observational constraint on gas-phase atomic sulfur abundance in dense cores using NS radical measurements.

Findings

Atomic sulfur is not depleted in early-type cores.

Sulfur depletion increases with core density.

Atomic sulfur abundance can reach cosmic levels in early stages.

Abstract

The abundance of volatile sulfur in dense clouds is long-standing problem in studies of the physics and chemistry of star-forming regions. Sulfur is an important species because its low ionization potential may possibly make it an important charge carrier. The observed sulfur-bearing species in the gas-phase of dense clouds represent only a minor fraction of the cosmic sulfur abundance, which has been interpreted as a signature of sulfur depletion into ices at the surface of dust grains. However, atomic sulfur, which could be the main gas-phase carrier, cannot be observed directly in cold cores. We present measurements of the nitrogen sulfide (NS) radical toward four dense cores performed with the IRAM-30m telescope. Analytical chemical considerations and chemical models over a wide parameter space show that the NS:N2H+ abundance ratio provides a direct constraint on the abundance of gas-phase atomic sulfur. Toward early-type cores, we find that $n(\rm S)/n_{\rm H}$ is close, or even equal, to the cosmic abundance of sulfur, 14$\times 10^{-6}$, demonstrating that sulfur is not depleted and is atomic, which is in agreement with chemical models. More chemically evolved cores show sulfur depletion by factors up to 100 in their densest parts. In L1544, atomic sulfur depletion is shown to increase with increasing density. Future observations are needed to discover the solid-phase carrier of sulfur. The initial steps of the collapse of pre-stellar cores in the high sulfur abundance regime also need to be explored from their chemical and dynamical perspectives.