Structural studies of the sol-gel glasses with copper selenide nanoparticles by SANS technique

TL;DR

This study investigates the nanostructure of copper selenide-doped sol-gel silica glasses using SANS and TEM, revealing complex particle-matrix interactions and fractal structures.

Contribution

It introduces a multi-model approach to analyze SANS data, providing detailed insights into nanoparticle sizes and the glass matrix modifications.

Findings

Cu2Se particles are approximately 60nm in size.

The glass matrix shows long-range structural modifications.

Fractal dimension indicates complex 'particle-in-glass' structures.

Abstract

The sol-gel silica glasses doped with copper selenide nanoparticles were studied through small-angle neutron scattering (SANS) and transmission electron microscopy. SANS intensities demonstrate the complicated dependence on the scattering parameter (transferred momentum within the framework of this technique), however, with no pronounced peaks throughout the full q interval. The multi-component power-law-exponential model was applied for the approximation and evaluation of the scattering objects sizes at different levels. Also, fitting to the mono-exponential fractal model was elaborated for SANS data. From the results of both simulations we derive the sizes of Cu2Se particles about 60nm and the noticeable modification of the glass matrix at the scale of the one order more (the long-range effect of particles upon the glass). The fractal dimension of the above scattering objects is varied from 1.5 through 4.2 indicating the formation of complex structure 'particle-in-glass' which may not be reduced to a simple model of single particles in solid matrix.