Comparison of hydrogen diffusivities measured by electrochemical permeation and temperature-programmed desorption in cold-rolled pure iron

TL;DR

This study compares hydrogen diffusivities in cold-rolled pure iron measured by electrochemical permeation and temperature-programmed desorption, demonstrating that TDS-based desorption experiments reliably estimate diffusivity across various temperatures.

Contribution

It introduces a method using isothermal desorption experiments with TDS systems to accurately determine hydrogen diffusivity over a wide temperature range.

Findings

Good agreement between desorption and permeation methods.

Measured diffusivities align with literature values.

Isothermal desorption is a convenient alternative for diffusivity measurement.

Abstract

The diffusivity of hydrogen in cold-rolled pure iron is investigated using permeation and desorption methods. Electrochemical charging, electro-permeation and thermal desorption spectroscopy (TDS) experiments are conducted. Firstly, the relation between the charging current and the hydrogen concentration is established. Secondly, permeation experiments are conducted at 22, 40 and 67{\deg}C to quantify the diffusivity dependence on temperature. Finally, the diffusivity is estimated by using two types of desorption experiments and Fick's law: (i) a `rest time' method, by which we measure the hydrogen content of samples held at room temperature for different times, and (ii) isothermal desorption experiments at temperatures ranging from 22 to 80{\deg}C, fitting the resulting desorption rate versus time curves. Good agreement is obtained between the isothermal desorption and permeation approaches, with observed differences discussed and rationalised. Moreover, measured diffusivity values for cold-rolled pure iron are also found to be comparable to those reported in the literature. This work demonstrates that isothermal desorption experiments are a convenient approach to determine hydrogen diffusivity over a wide range of temperatures, as facilitated by new TDS systems with fast heating rates.