Titanium oxide and chemical inhomogeneity in the atmosphere of the exoplanet WASP-189b
Bibiana Prinoth, H. Jens Hoeijmakers, Daniel Kitzmann, Elin Sandvik,, Julia V. Seidel, Monika Lendl, Nicholas W. Borsato, Brian Thorsbro, David R., Anderson, David Barrado, Kateryna Kravchenko, Romain Allart, Vincent, Bourrier, Heather M. Cegla, David Ehrenreich, Chloe Fisher

TL;DR
This study unambiguously detects titanium oxide and various metals in the atmosphere of the ultra-hot Jupiter WASP-189b, revealing chemical inhomogeneity and three-dimensional stratification through high-resolution spectroscopy.
Contribution
It provides the first clear detection of TiO in WASP-189b using high-resolution transmission spectroscopy and demonstrates chemical inhomogeneity in its atmosphere.
Findings
Detection of TiO, Fe, Fe+, Ti+, Cr, Mg, V, Mn in WASP-189b's atmosphere
Evidence of spatial chemical gradients and stratification
Confirmation of complex thermo-chemical structure in exoplanet atmospheres
Abstract
The temperature of an atmosphere decreases with increasing altitude, unless a shortwave absorber exists that causes a temperature inversion. Ozone plays this role in the Earth`s atmosphere. In the atmospheres of highly irradiated exoplanets, shortwave absorbers are predicted to be titanium oxide (TiO) and vanadium oxide (VO). Detections of TiO and VO have been claimed using both low and high spectral resolution observations, but later observations have failed to confirm these claims or overturned them. Here we report the unambiguous detection of TiO in the ultra-hot Jupiter WASP-189b using high-resolution transmission spectroscopy. This detection is based on applying the cross-correlation technique to many spectral lines of TiO from 460 to 690 nm. Moreover, we report detections of metals, including neutral and singly ionised iron and titanium, as well as chromium, magnesium, vanadium…
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