Characterization of the (Cu,C)Ba$_2$Ca$_3$Cu$_4$O$_{11+\delta}$ single crystals grown under high pressure

TL;DR

This study successfully grew high-quality (Cu,C)Ba$_2$Ca$_3$Cu$_4$O$_{11+ heta}$ single crystals under high pressure, characterizing their structural, electrical, and magnetic properties, revealing promising superconducting and magnetic features.

Contribution

First demonstration of high-pressure synthesis of (Cu,C)Ba$_2$Ca$_3$Cu$_4$O$_{11+ heta}$ single crystals with detailed property characterization.

Findings

Transition temperatures of about 111 K and 109.6 K with narrow transition width.

Pronounced second peak effect in magnetization hysteresis loops.

Magnetic critical current density of approximately 6.4×10^4 A/cm^2 at 77 K and 1.5 T.

Abstract

By using high pressure and high temperature (3.7 GPa, 1120 $^{\circ}$C) synthesis technique, we have grown (Cu,C)Ba$_2$Ca$_3$Cu$_4$O$_{11+\delta}$ single crystals. X-ray diffraction, scanning electron microscopy, resistivity and magnetization measurements are carried out and all show that the samples have good quality. The single crystal has onset and zero-resistance transition temperatures of about 111 K and 109.6 K, indicating a very narrow transition width, which is consistent with a rather sharp magnetization transition. Magnetization hysteresis loops (MHLs) are also measured, showing a pronounced second peak effect in the intermediate temperature region. The magnetic critical current density calculated from the MHLs at 77 K and 1.5 T is about 6.4$\times$10$^4$ A/cm$^2$. By using a criterion of 1$\%$ normal state resistivity, we have determined the irreversibility line which exhibits an irreversibility field of about 8 T at 77 K. Compared with other layered systems, it is easy to find that the irreversibility line is rather high and could be further improved with the optimized transition temperature of about 118 K as previously discovered in polycrystalline samples.