Inducing and tuning Kondo screening in a narrow-electronic-band system

TL;DR

This paper demonstrates how Pb intercalation in 1T-TaS2 induces and tunes Kondo screening in a narrow-electronic-band system, revealing a transition from insulating to Kondo resonance states and enabling control over many-body electronic phenomena.

Contribution

It shows the creation and tuning of Kondo lattice states in a non-f-electron layered material through chemical intercalation, advancing understanding of Kondo physics beyond traditional systems.

Findings

Pb intercalation induces a Kondo resonance in 1T-TaS2.

Increasing Pb concentration suppresses the Kondo resonance.

The results confirm cluster Mott localization and local moment formation.

Abstract

Although the single-impurity Kondo physics has already been well understood, the understanding of the Kondo lattice problem where a dense array of local moments couples to the conduction electrons is still far from complete. The ability of creating and tuning the Kondo lattice in non-f-electron systems will be great helpful for further understanding the Kondo lattice behavior. Here we show that the Pb intercalation in the charge-density-wave-driven narrow-electronic-band system 1T-TaS2 induces a transition from the insulating gap to a sharp Kondo resonance in the scanning tunneling microscopy measurements. It results from the Kondo screening of the localized moment in the 13-site Star-of-David clusters of 1T-TaS2, and thus confirms the cluster Mott localization of the unpaired electrons and local moment formation in the 1T-TaS2 layer. As increasing the Pb concentration, the narrow electronic band derived from the localized electrons shifts away from the Fermi level and the Kondo resonance peak is gradually suppressed. Our results pave a way for creating and tuning many-body electronic states in layered narrow-electronic-band materials.