Observations of multiple NH$_3$ transitions in W33

TL;DR

This study presents ammonia transition observations in the W33 star-forming complex, revealing physical properties, chemical abundances, and evolutionary stages of its molecular clouds, with no hot core detected and ammonia formation likely occurring in gas or on dust grains.

Contribution

First detailed ammonia multi-transition measurements in W33, providing insights into physical conditions and chemical processes in a massive star-forming complex.

Findings

Detected multiple NH3 inversion lines, including maser emission.

Determined kinetic temperatures and column densities across W33.

Confirmed different evolutionary stages of W33 clumps without hot cores.

Abstract

At a distance of 2.4kpc, W33 is an outstanding massive and luminous 10pc sized star forming complex containing quiescent infrared dark clouds as well as highly active infrared bright cloud cores heated by young massive stars. We report measurements of ammonia (NH$_3$) inversion lines in the frequency range 18--26GHz, obtained with the 40" resolution of the 100 m Effelsberg telescope. We have detected the ($J$, $K$)=(1,1), (2,2), (3,3), (4,4), (5,5), (6,6), (2,1) and (3,2) transitions. There is a maser line in the (3,3) transition towards W33 Main. Brightness temperature and line shape indicate no significant variation during the last $\sim$36yr. We have determined kinetic temperatures, column densities and other physical properties of NH$_3$ and the molecular clouds in W33. For the total-NH$_3$ column density, we find for 40"(0.5pc) sized regions 6.0($\pm$2.1)$\times$10$^{14}$, 3.5($\pm$0.1)$\times$10$^{15}$, 3.4($\pm$0.2)$\times$10$^{15}$, 3.1($\pm$0.2)$\times$10$^{15}$, 2.8($\pm$0.2)$\times$10$^{15}$ and 2.0($\pm$0.2)$\times$10$^{15}$cm$^{-2}$ at the peak positions of W33 Main, W33 A, W33 B, W33 Main1, W33 A1 and W33 B1, respectively. W33 Main has a total-NH$_3$ fractional abundance of 1.3($\pm$0.1)$\times$10$^{-9}$ at the peak position. High values of 1.4($\pm$0.3)$\times$10$^{-8}$, 1.6($\pm$0.3)$\times$10$^{-8}$, 3.4($\pm$0.5)$\times$10$^{-8}$, 1.6($\pm$0.5)$\times$10$^{-8}$ and 4.0($\pm$1.2)$\times$10$^{-8}$ are obtained at the central positions of W33 A, W33 B, W33 Main1, W33 A1, and W33 B1. From this, we confirm the already previously proposed different evolutionary stages of the six W33 clumps and find that there is no hot core in the region approaching the extreme conditions encountered in W51-IRS2 or Sgr B2. The ortho-to-para-NH$_3$ abundance ratios suggest that ammonia should have been formed in the gas phase or on dust grain mantles at kinetic temperatures of $\gtrsim$20K.