Gluconate and hexitols effects on C-S-H solubility

TL;DR

This study explores how gluconate and hexitols influence C-S-H solubility through thermodynamic modeling and adsorption experiments, revealing complex formation and adsorption behaviors that depend on pH, calcium, and organic concentration.

Contribution

It provides new insights into the interactions between specific organic molecules and C-S-H, including complexation and adsorption mechanisms, under various chemical conditions.

Findings

Gluconate forms the strongest complexes with calcium and silicate.

Adsorption on C-S-H increases with Ca/Si ratio and organic concentration.

Heteropolynuclear complexes are observed at high pH and calcium levels.

Abstract

This study investigates the effect of gluconate, a carboxylate ion, and three uncharged hexitols, D-sorbitol, D-mannitol and D-galactitol on the solubility of C-S-H. Thermodynamic modeling was used to determine the kind and amount of Ca-organic-silicate-OH complexes that potentially form in the conditions studied. All the organics form complexes with calcium and hydroxide, In addition, heteropolynuclear organics complexes with calcium, hydroxide and silicate are observed at high pH values and high calcium concentrations with the exception of mannitol. The strength of complexation with silicate decreases from gluconate > sorbitol > galactitol. The adsorption of the selected organics on portlandite and C-S-H systems follows the order gluconate >> sorbitol > mannitol = galactitol. For C-S-H system buffered with Ca(OH)2, a typical Langmuir isotherm was found and adsorption on C-S-H increased with the Ca/Si ratio as well as with the increase of the organic concentration.