Diethyl Sulfoxide as a Novel Neutral Ligand in the Platinum Complex Anion

TL;DR

This study uses computational methods to analyze the stability and structure of a platinum complex with diethyl sulfoxide (DESO) as a neutral ligand, revealing limitations on ligand number and explaining its high melting point.

Contribution

It provides the first computational explanation for the stability and structural features of a platinum complex with DESO as a neutral ligand, expanding understanding of sulfoxide coordination chemistry.

Findings

Only up to two DESO molecules are stable in the platinum complex.

Higher DESO contents are thermodynamically unstable due to steric effects.

The complex exhibits strong cation-anion coordination and a high melting point.

Abstract

Diethyl sulfoxide (DESO) is far less known than its shorter-alkyl-chain homolog, dimethyl sulfoxide. Although the field of senior dialkyl sulfoxides does not currently exhibit an explosive growth, new fundamental and applied research works routinely appear from a few research groups in the world. Recently, the tetraethylammonium diethylsulfoxidopentachloroplatinate complex compound was synthesized containing the DESO molecule as a neutral ligand. In the present paper, we use a systematic computational method to rationalize the mentioned synthetic achievement in coordination chemistry. We show that only up to two DESO molecules may exist in the platinum (IV) complex ion, whereas all higher contents of DESO are thermodynamically unstable and the sterical factor plays an important role in their instabilities. Structural analysis of the tetraethylammonium diethylsulfoxidopentachloroplatinate ion pair reveals its rather strong cation-anion coordination and for the first time explains an experimentally derived high melting point. The reported results are expected to inspire experimental efforts to extend the universe of senior sulfoxides as neutral organic ligands in d-metal complexes.