Network-based membrane filters: Influence of network and pore size variability on filtration performance

TL;DR

This study models porous membrane filters as networks with variable pore sizes to understand how network and pore size variability affect filtration performance, especially under fouling conditions.

Contribution

It introduces a network-based model with variable pore radii to analyze the impact of pore size and network variability on membrane filtration performance.

Findings

Porosity variations significantly influence filter performance.

Pore radius variability increases throughput but reduces foulant control.

Network and pore size variations are critical factors in filtration efficiency.

Abstract

We model porous membrane filters as networks of connected cylindrical pores via a random network generation protocol, and their initial pore radii via a uniform distribution of widths that vary about some mean value. We investigate the influence of network and pore size (radius) variations on the performance of membrane filters that undergo adsorptive fouling. We find that membrane porosity variations, independently of whether induced by variations of the pore radii or of the random pore network, are an important factor determining membrane filter performance. Network and pore size variations still play a role, in particular if pore radii variations are significant. To quantify the influence of these variations, we compare the performance metrics of networks built from pores of variable radii to their (equal porosity) counterparts built from pores of uniform radius. We show that the effect of pore radii variations is to increase throughput, but also to reduce foulant control.