Phonon Anomaly In 9R-Ba0.9Sr0.1MnO3

TL;DR

This study investigates the coupling between vibrational and magnetic properties in 9R-Ba0.9Sr0.1MnO3, revealing a phonon anomaly at 260 K linked to spin-phonon interactions and magnetic ordering.

Contribution

It provides the first detailed analysis of spin-phonon coupling in 9R-Ba0.9Sr0.1MnO3, highlighting the phonon anomaly associated with magnetic transition.

Findings

Observation of nine characteristic Raman modes.

Anomaly in the Eg phonon mode at 260 K.

Correlation between phonon behavior and magnetic ordering.

Abstract

Materials which possess coupling between different degrees of freedom such as charge, spin, orbital and lattice are of tremendous interest due to their potential for device applications. It has been recently realized that some of manganite perovskite oxides show structural and ferroelectric instabilities which may be tuned by imposing internal or external strain. Among manganite perovskites, AMnO3 (A = Ca, Sr and Ba) are reported to be good candidates to show spin-phonon coupling driven multiferroicity. Here, we have probed the correlation between vibrational and magnetic properties in the 9R-type hexagonal Ba0.9Sr0.1MnO3 (BSM10). Nine Raman active modes are observed which are characteristic phonon modes for 9R phase. The frequency ({omega}) of an Eg (344 cm-1) mode which is related to Mn vibrations shows anomaly with temperature (T) manifested as a change in slope of {omega} vs T at 260 K. The temperature-dependent magnetization of BSM10 suggests a possible antiferromagnetic ordering at ~ 260 K. We, therefore, attribute the phonon anomaly to spin-phonon coupling arising due to the magnetic ordering.