Long-Lived Highly Emissive MOFs as Potential Candidates for Multiphotonic Applications

TL;DR

This study demonstrates how different crystalline structures of MOFs can exhibit long-lived RTP and TADF emissions, highlighting their potential in photonic applications like sensors, security, lighting, and MOF-LEDs.

Contribution

It reveals the relationship between linker arrangement in MOFs and their emission properties, advancing the design of MOFs for optical applications.

Findings

Denser MOF shows long-lived green RTP due to hyperfine coupling.

Porous MOF exhibits temperature-dependent turquoise TADF emission.

First example of a MOF-LED based on RTP-MOFs.

Abstract

Long-lived emissive materials based on room temperature phosphorescence (RTP) and thermally activated delayed fluorescence (TADF) are considered as the cornerstone of the development of optical sensors, security systems and solid-state lighting. Nevertheless, molecular systems with these properties are scarce because most of them suffer from aggregation caused quenching emission (ACQ). One approach to address this shortcoming is by inhibiting the molecular motions/vibrations by employing a fixed matrix as afforded by a metal-organic framework (MOF). There, the organic chromophores are confined in a crystalline framework, and the structure-property relationship can be designed to get RTP/TADF. Inspired by this, the present work explores the relation between the linker arrangement and the physicochemical properties of two isochemical MOFs with different crystalline structures. The denser MOF exhibits a long-lived green RTP due to a hyperfine coupling of the linkers. On the other hand, the more porous MOF presents a long-lived temperature-dependent turquoise emission, reflecting the influence of the TADF. Hence, this study provides a huge advance about the potential of MOFs to undergo RTP and TADF emission, and at the same time, demonstrates their potential applicability in a wide range of photonic technologies, including physical and chemical sensing and the first example of a MOF-LED based on RTP-MOFs.