Organic ferroelectric Croconic Acid: A concise survey from bulk single crystals to thin films

TL;DR

This paper reviews the recent scientific progress on croconic acid, an organic ferroelectric material, highlighting its properties, origins of ferroelectricity, and potential applications in bulk crystals and thin films.

Contribution

It provides a comprehensive survey of croconic acid's ferroelectric properties, origins, and applications, bridging bulk and thin film forms for the first time.

Findings

Croconic acid exhibits above-room-temperature ferroelectricity with large polarization.

Both bulk and thin film forms of croconic acid are viable for device applications.

The origin of ferroelectric order in croconic acid is discussed in detail.

Abstract

Owing to prospective energy-efficient and environmentally benign applications, organic ferroelectric materials are useful and necessary alternative to inorganic ferroelectrics. Although the first discovered ferroelectric, Rochelle salt, was a salt of an organic compound, organic ferroelectrics have not been as abundant as the inorganic ones. Further, the small polarization values in the organic systems discovered so far have been a demotivating factor for their applications. However, scientific interest and activities surrounding such materials, for the purpose of fundamental understanding and practical applications, have significantly risen lately, especially after the discovery of above-room-temperature ferroelectricity in croconic acid (4,5-dihydroxy-4-cyclopentene-1,2,3-trione, H2C5O5) crystals with polarization values rivalling those found in inorganic ferroelectrics. Its large polarization, organic nature, and vacuum sublimability make croconic acid an ideal candidate for non-toxic and lead-free device applications. In this review article, we survey the scientific activities carried out so far involving ferroelectricity in this novel material, paying equal attention to its bulk single crystal and thin film forms. While we discuss about the origin of ferroelectric order and the reversal of polarization in the bulk form, we also summarize the directions toward applications of the thin films.