Magnetically collected platinum/nickel alloy nanoparticles -- insight into low noble metal content catalysts for hydrogen evolution reaction

TL;DR

This paper presents a novel low-noble-metal platinum/nickel alloy nanoparticle catalyst with a nanotruss structure that exhibits excellent hydrogen evolution reaction activity and stability, supported by both experimental results and theoretical insights.

Contribution

It introduces a new synthesis method for low-noble-metal PtxNi1-x nanotruss catalysts with high activity and stability for HER, combining experimental and theoretical analysis.

Findings

Pt0.05Ni0.95 nanotrusses show a Tafel slope of 30 mV/dec

Overpotential of 20 mV at 10 mA/cm² in 0.5 M H2SO4

High stability during electrochemical testing

Abstract

The hydrogen evolution reaction (HER) is a key process in electrochemical water splitting. To lower the cost and environmental impact of this process, it is highly motivated to develop electrocatalysts with low or no content of noble metals. Here we report on a novel and ingenious synthesis of hybrid PtxNi1-x electrocatalysts in the form of a nanoparticle-necklace structure named nanotrusses, with very low noble metal content. The nanotruss structure possesses important features, such as good conductivity, high surface area, strong interlinking and substrate adhesion, which renders for an excellent HER activity. Specifically, the best performing Pt0.05Ni0.95 sample, demonstrates a Tafel slope of 30 mV dec-1 in 0.5 M H2SO4, and an overpotential of 20 mV at a current density of 10 mA cm-2 with high stability. The impressive catalytic performance is further rationalized in a theoretical study, which provides insight into the mechanism for how such small platinum content can allow for close-to-optimal adsorption energies for hydrogen.