Generalized Fresnel-Floquet equations for driven quantum materials

TL;DR

This paper develops a Floquet-based phenomenological model to explain unusual optical properties observed in driven quantum materials, such as transient reflectivity features and photo-induced edges, with applications to superconductors and polariton systems.

Contribution

It introduces a universal Floquet formalism for driven quantum materials, accounting for parametric excitation and dissipation, and applies it to explain experimental observations in superconductors and polaritons.

Findings

Universal phase diagram of drive-induced reflectivity features

Model accurately fits phonon-pump terahertz-probe experiments

Explains pump-induced edges higher than equilibrium Josephson plasmon edges

Abstract

Optical drives at terahertz and mid-infrared frequencies in quantum materials are increasingly used to reveal the nonlinear dynamics of collective modes in correlated many-body systems and their interplay with electromagnetic waves. Recent experiments demonstrated several surprising optical properties of transient states induced by driving, including the appearance of photo-induced edges in the reflectivity in cuprate superconductors, observed both below and above the equilibrium transition temperature. Furthermore, in other driven materials, reflection coefficients larger than unity have been observed. In this paper we demonstrate that unusual optical properties of photoexcited systems can be understood from the perspective of a Floquet system; a system with periodically modulated system parameters originating from pump-induced oscillations of a collective mode. We present a general phenomenological model of reflectivity from Floquet materials, which takes into account parametric generation of excitation pairs. We find a universal phase diagram of drive induced features in reflectivity which evidence a competition between driving and dissipation. To illustrate our general analysis we apply our formalism to two concrete examples motivated by recent experiments: a single plasmon band, which describes Josephson plasmons in layered superconductors, and a phonon-polariton system, which describes upper and lower polaritons in materials such as insulating SiC. Finally we demonstrate that our model can be used to provide an accurate fit to results of phonon-pump - terahertz-probe experiments in the high temperature superconductor $\rm{YBa_2Cu_3O_{6.5}}$. Our model explains the appearance of a pump-induced edge, which is higher in energy than the equilibrium Josephson plasmon edge, even if the interlayer Josephson coupling is suppressed by the pump pulse.