Thermal stability of interfacial mixed layers in c-Ni/a-Zr multilayer during annealing: structural and magnetic properties

TL;DR

This study investigates how annealing affects the structural and magnetic stability of c-Ni/a-Zr multilayers, revealing interfacial mixing, demixing effects, and increased magnetic moments at elevated temperatures.

Contribution

It provides detailed insights into the thermal stability and atomic transport mechanisms at interfaces in c-Ni/a-Zr multilayers during annealing.

Findings

Interfacial widths increase with annealing temperature.

Ni-on-Zr interface is unstable at both 200°C and 400°C.

Annealing at 400°C enhances magnetic moment due to densification and Ni crystallite incorporation.

Abstract

Annealing of crystalline multilayers composed of two miscible elements usually causes interfacial mixing of the constituent atoms, possibly leading to the formation of binary alloys at the interfaces. Magnetron sputtered c-Ni/a-Zr multilayers deposited at room temperature were vacuum annealed isochronally at 200degC and 400degC to observe thermal stability of the interfaces constituting the crystalline/amorphous multilayers. Control over the interfacial behaviour can aid the formation of materials with novel properties. The resultant changes in structural and magnetic properties of the multilayers were investigated in detail through X-ray Reflectivity, Polarized Neutron Reflectivity, SIMS and SQUID-based magnetization measurement techniques. The compositional variations in the amorphous mixed layers formed at the Ni-on-Zr and Zr-on-Ni interfaces due to atomic transport, were carefully observed as a function of annealing. Interface widths proceeded to increase with annealing at the expense of the Ni and Zr layers. The Ni-on-Zr interface was seen to be unstable at both temperatures; but the overall response of the interfaces to atomic diffusion was more pronounced when the multilayers were annealed at 400degC. Under conditions of supersaturation of atoms within restricted spaces of the interfacial layers and the limited availability of components within the multilayer, unexpected demixing effects were observed at both the interfaces. A large increase in magnetic moment obtained after annealing at 400degC, was attributed to the high densification of the Ni layers as well as to the incorporation of Ni crystallites into the Zr-on-Ni interface layers.