Magnetic structure of Tb3RuO7 possessing alternating-bond spin-3/2 Ru chains in a nonuniform internal magnetic field: appearance of a partially disordered state

TL;DR

This study reveals a partially disordered magnetic state in Tb3RuO7 due to alternating-bond Ru chains and nonuniform internal magnetic fields, contrasting with the ordered state in Nd3RuO7, based on neutron diffraction experiments.

Contribution

It demonstrates the emergence of a partially disordered state in Tb3RuO7 caused by magnetic frustration and nonuniform internal fields, highlighting the role of internal magnetic field differences.

Findings

Tb3RuO7 exhibits a partially disordered state below 15 K.

Nd3RuO7 shows ordered moments in both Ru sites below 17.5 K.

Nonuniform internal magnetic fields influence the magnetic states.

Abstract

We report on the magnetic structures of Tb3RuO7 and Nd3RuO7 determined from powder neutron-diffraction experiments. In Tb3RuO7, alternating-bond spin-3/2 Ru1-Ru2 chains are formed. The Ru1 and Ru2 moments are ordered and disordered (paramagnetic), respectively, below 15 K. This result indicates the appearance of a partially disordered (PD) state, although the two Ru sites are very similar to each other. In Nd3RuO7, the Ru1 and Ru2 ions form independent uniform chains. Both the Ru1 and Ru2 moments are ordered below 17.5 K. Probably, the main source of the PD state in Tb3RuO7 is the magnetic frustration in the exchange interactions. The internal magnetic field generated by the Tb ordered moments at the Ru1 sites is different from that at the Ru2 sites. We speculate that the different (nonuniform) internal magnetic field enhances the difference in the properties between the Ru1 and Ru2 moments.