Giant shifts of crystal-field excitations in ErFeO3 driven by internal magnetic fields

TL;DR

This study reveals large shifts in Er3+ crystal-field excitations in ErFeO3 caused by internal magnetic fields, supported by neutron scattering and theoretical modeling, highlighting complex magnetic interactions in rare-earth transition-metal oxides.

Contribution

The paper introduces a comprehensive CF model explaining the significant energy shifts of Er3+ excitations driven by internal magnetic fields in ErFeO3, supported by experimental and theoretical evidence.

Findings

Observed CF excitation shift from 0.35 to 0.75 meV with temperature change.

Derived internal magnetic field of 0.33 meV acting on Er3+.

Identified strong anisotropy in the effective g-factor for Er3+.

Abstract

Due to the complex interactions between rare-earth elements and transition metals, as well as/or themselves, rare-earth transition-metal oxides are likely to exhibit highly intriguing and novel magnetic structures and dynamic behaviours. Rare-earth elements in these compounds frequently demonstrate unusual behaviours in their crystal-field (CF) excitations, which necessitate thorough research for in-depth comprehensions. When cooling from 10 K to 1.5 K via the magnetic ordering temperature of Er3+ at 4.1 K, we observed a significant energy shift of the low-lying CF excitation of Er3+ in ErFeO3 from 0.35 meV to 0.75 meV utilizing the inelastic neutron-scattering technique. A sound CF model was proposed for Er3+ in ErFeO3 by fitting to the observed CF excitation peaks, which enables to explain all the observed experimental results in a very consistent manner. According to the model, the ground crystal field level of Er3+, which corresponds to the lowest Kramers doublet supposed to be at zero energy, has been shifted by the internal magnetic fields induced by both Er3+ and Fe3+ spin orders below and above the Er3+ ordering temperature, respectively. Additional measurements in various magnetic fields offer compelling evidence in favour of this hypothesis. The measured external field dependence of the CF excitation energy led to the derivation of the internal field of Er3+ as 0.33 meV, which is strongly corroborated by theoretical modelling. Additionally, the effective g-factor for Er3+ in ErFeO3 showed an exceptionally significant anisotropy.