Interlayer bonding investigation of 3D printing cementitious materials with fluidity retaining polycarboxylate superplasticizer and high dispersion polycarboxylate superplasticizer

TL;DR

This study investigates how different polycarboxylate superplasticizers affect the rheological properties and interlayer bonding strength of 3D printed cementitious materials, highlighting the benefits of fluidity retaining superplasticizer.

Contribution

It introduces the use of fluidity retaining polycarboxylate superplasticizer to improve rheology and bonding in 3D printing cementitious materials, providing new insights into interlayer adhesion control.

Findings

FR PC enhances fluidity retention and thixotropy.

FR PC improves interlayer bonding strength over time.

FR PC reduces the decrease in bonding strength with longer time intervals.

Abstract

Proposed special requirements exist for the rheological properties and time varying characteristics of 3D printing cementitious materials (3DPC). In this study, high dispersion polycarboxylate superplasticizer (HD PC) and fluidity retaining polycarboxylate superplasticizer (FR PC) were used to control the rheological behaviors of 3DPC. The correlation of the time interval, the time varying characteristics of the rheological properties and the interlayer bonding strength were investigated. The results indicated that FR PC improved the fluidity retention ability and thixotropy of the fresh pastes. The thixotropic hysteresis loop area and reflocculation rate (Rthix) of FR PC were 101.9% and 80.4% higher than those of HD PC, respectively. Furthermore, the FR PC polymer has a positive effect on the interlayer bonding and may reduce the negative effect caused by extending the time interval. During the time interval of 20 s to 30 min, the interlayer bonding strength with FR PC decreases by 14.1%, while that with HD PC decreases by 50.0%.