Spin-orbit induced equilibrium spin currents in materials

TL;DR

This paper reveals that equilibrium spin currents are a common feature in materials with significant spin-orbit coupling, arising from symmetry and gauge theory analogies, and are crucial for understanding spin transport.

Contribution

It demonstrates the general presence of equilibrium spin currents in materials with SOC, using symmetry analysis and first-principles calculations, expanding the understanding beyond quantum materials.

Findings

Equilibrium spin currents exist at surfaces and in bulk of SOC materials.

Symmetry considerations allow equilibrium spin currents in gyrotropic systems.

First-principles calculations quantify these currents in various materials.

Abstract

The existence of spin-currents in absence of any driving external fields is commonly considered an exotic phenomenon appearing only in quantum materials, such as topological insulators. We demonstrate instead that equilibrium spin currents are a rather general property of materials with non negligible spin-orbit coupling (SOC). Equilibrium spin currents can be present at the surfaces of a slab. Yet, we also propose the existence of global equilibrium spin currents, which are net bulk spin-currents along specific crystallographic directions of materials. Equilibrium spin currents are allowed by symmetry in a very broad class of systems having gyrotropic point groups. The physics behind equilibrium spin currents is uncovered by making an analogy between electronic systems with SOC and non-Abelian gauge theories. The electron spin can be seen as the analogous of the color degree of freedom and equilibrium spin currents can then be identified with diamagnetic color currents appearing as the response to an effective non-Abelian magnetic field generated by SOC. Equilibrium spin currents are not associated with spin transport and accumulation, but they should nonetheless be carefully taken into account when computing transport spin currents. We provide quantitative estimates of equilibrium spin currents for several systems, specifically metallic surfaces presenting Rashba-like surface states, nitride semiconducting nanostructures and bulk materials, such as the prototypical gyrotropic medium tellurium. In doing so, we also point out the limitations of model approaches showing that first-principles calculations are needed to obtain reliable predictions. We therefore use Density Functional Theory computing the so-called bond currents, which represent a powerful tool to understand the relation between equilibrium currents, electronic structure and crystal point group.