Synthesis and Anisotropic Magnetism in Quantum Spin Liquid Candidates $A$YbSe$_2$ ($A$ = K and Rb)

TL;DR

This study reports the synthesis, crystal structure, and magnetic properties of $A$YbSe$_2$ ($A$=K, Rb), revealing anisotropic magnetism, potential quantum spin liquid behavior, and unique frustrated magnetic states in these layered compounds.

Contribution

It provides the first detailed synthesis, structural characterization, and magnetic analysis of $A$YbSe$_2$ compounds, highlighting their potential as quantum spin liquid candidates.

Findings

No long-range magnetic order down to 0.4 K.

Presence of a one-third magnetization plateau in $ab$-plane.

Characteristic dome in heat capacity indicating frustrated magnetism.

Abstract

Quantum spin liquid (QSL) state in rare-earth triangular lattice has attracted much attention recently due to its potential application in quantum computing and communication. Here we report the single-crystal growth synthesis, crystal structure characterizations and magnetic properties of $A$YbSe$_{2}$ ($A$= K, Rb) compounds. The X-ray diffraction analysis shows that $A$YbSe$_{2}$ ($A$ = K and Rb) crystallizes in a trigonal space group, $R$-3$m$ (No. 166) with Z = 3. $A$YbSe$_{2}$ possesses a two-dimensional (2D) Yb-Se-Yb layered structure formed by edged-shared YbSe$_6$ octahedra. The magnetic properties are highly anisotropic for both title compounds and no long-range order is found down to 0.4 K, revealing the possible QSL ground state in these compounds. The isothermal magnetization exhibits one-third magnetization plateau when the magnetic fields are applied in $ab$-plane. Heat capacity is performed along both $ab$-plane and $c$-axis, and features the characteristic dome for triangular magnetic lattice compounds as a function of magnetic fields. Due to the change of the interlayer and intralayer distance of Yb$^{3+}$, the dome shifts to low fields from KYbSe$_2$ to RbYbSe$_2$. All these results indicate the $A$YbSe$_2$ family presents unique frustrated magnetism close to the possible QSL and noncolinear spin states.