An overview of the structural correlation of magnetic and electrical properties of Pr2NiMnO6 Double perovskite

TL;DR

This review summarizes the structural, magnetic, and electrical properties of Pr2NiMnO6, highlighting its potential applications and the need for detailed structural studies like neutron diffraction to better understand its properties.

Contribution

It provides a comprehensive overview of Pr2NiMnO6, comparing it with other RNMO double perovskites and emphasizing the importance of detailed structural analysis.

Findings

Pr2NiMnO6 exhibits spin-phonon coupling and magnetocaloric effects.

Structural distortions influence magnetic and electrical properties.

Comparison with other RNMO compounds highlights unique features of PNMO.

Abstract

Double perovskites R2NiMnO6 (R= Rare earth element) (RNMO) are a significant class of materials owing to their varied tunability of the magnetic and electrical properties with the structural modifications. Pr2NiMnO6 (PNMO) is one of the least explored members of this series, which shows spin-phonon coupling, magnetocaloric effect, and electrochemical performance for various applications such as spintronics, magnetocaloric refrigerant, and solid oxide fuel cells. Most of the studies in PNMO are limited to the application domain and focus on the comparative study with different rare earth elements. Detailed structural studies like neutron diffraction are sparse in PNMO samples which will give a perception to the ordering in the compound that strongly depends on the physical and chemical properties. This review article goes through the various aspects of PNMO materials that have been reported till now and showcase the octahedral distortions and corresponding structural changes and the exchange interactions, which in turn correlates with the magnetic and electrical properties. The comparison study of PNMO with other members of the RNMO family and the relevance of PNMO over other members is also tried to showcase through this article. Hope this article provides an insight into the scope of studies in PNMO material for exploring unexposed properties of the materials in the double perovskite family.