Superexchange interactions in AgMF4 (M = Co, Ni, Cu) polymorphs

TL;DR

This study uses computational methods to explore superexchange interactions in AgMF4 compounds with M = Co, Ni, Cu, revealing how Ag(II) influences magnetic coupling and chain formation in various polymorphs.

Contribution

It provides the first detailed computational analysis of superexchange pathways and magnetic interactions in AgMF4 polymorphs, highlighting the effects of pressure and metal substitution.

Findings

AgCuF4 mainly exhibits Ag-Ag and Cu-Cu superexchange interactions.

Pressure and Ni substitution strengthen Ag-M superexchange interactions.

Strongest superexchange pathways form antiferromagnetic chains.

Abstract

Magnetic properties of silver(II) compounds have been of interest in recent years. In covalent compounds, the main mechanism of interaction between paramagnetic sites is the superexchange via the connecting ligand. To date, little is known of magnetic interactions between Ag(II) cations and other paramagnetic centres. It is because only a few compounds bearing Ag(II) cation and other paramagnetic transition metal cation are known experimentally. Recently the high-pressure synthesis of ternary silver(II) fluorides with 3d metal cations AgMF4 (M = Co, Ni, Cu) was predicted to be feasible. Here, we investigate the magnetic properties of these compounds in their diverse polymorphic forms. Using well established computational methods we predict superexchange pathways in AgMF4, evaluate coupling constants and calculate the impact of Ag(II) presence on superexchange between the other cations. The results indicate that the low-pressure form of AgCuF4, the only composed of stacked layers as the parent AgF2, would hold mainly Ag-Ag and Cu-Cu superexchange interactions. Upon compression, or with the nickel(II) cation, the Ag-M interactions in AgMF4 intensify, which is emphasized by an increase of Ag-M superexchange coupling constants and Ag-F-M angles. All the strongest Ag-M superexchange pathways are quasi-linear, leading to the formation of antiferromagnetic chains along the crystallographic directions. The impact of Ag(II) on M-M superexchange turns out to be moderate, due to factors connected to the crystal structure.