Confirmation of Iron Emission Lines and Non-detection of TiO on the Dayside of KELT-9b with MAROON-X
David H. Kasper, Jacob L. Bean, Michael R. Line, Andreas Seifahrt,, Julian St\"urmer, Lorenzo Pino, Jean-Michel Desert, Matteo Brogi

TL;DR
This study used high-resolution spectroscopy to confirm a thermal inversion in KELT-9b's atmosphere, detected atomic emission lines, and placed strict upper limits on TiO, challenging previous models and suggesting alternative explanations for the planet's spectrum.
Contribution
First high-resolution detection of atomic emission lines confirming thermal inversion on KELT-9b and constraining TiO abundance, challenging existing atmospheric models.
Findings
Confirmed thermal inversion via atomic emission lines.
Placed upper limit on TiO volume mixing ratio at 10^{-8.5}.
Found Fe+ abundance higher than model predictions.
Abstract
We present dayside thermal emission observations of the hottest exoplanet KELT-9b using the new MAROON-X spectrograph. We detect atomic lines in emission with a signal-to-noise ratio of 10 using cross-correlation with binary masks. The detection of emission lines confirms the presence of a thermal inversion in KELT-9b's atmosphere. We also use M-dwarf stellar masks to search for TiO, which has recently been invoked to explain the unusual \textit{HST}/WFC3 spectrum of the planet. We find that the KELT-9b atmosphere is inconsistent with the M-dwarf masks. Furthermore, we use an atmospheric retrieval approach to place an upper limit on the TiO volume mixing ratio of 10 (at 99\% confidence). This upper limit is inconsistent with the models used to match the WFC3 data, which require at least an order of magnitude more TiO, thus suggesting the need for an alternate explanation of the…
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