Direct Observation of Chiral Phonons by Inelastic X-ray Scattering

TL;DR

This study demonstrates that inelastic X-ray scattering can directly observe and characterize chiral phonons in materials, revealing their polarization and chirality across the Brillouin zone, which was previously challenging.

Contribution

It introduces a novel experimental approach using inelastic X-ray scattering to characterize phonon chirality throughout the full Brillouin zone.

Findings

Circular polarization of phonons near K and K' points in tungsten carbide.

Observation of anomalous inelastic X-ray scattering due to phonon chirality.

Validation that inelastic X-ray scattering can probe phonon chirality.

Abstract

Phonon chirality has attracted intensive attention since it breaks the traditional cognition that phonons are linear propagating bosons. This new quasiparticle property has been extensively studied theoretically and experimentally. However, characterization of the phonon chirality throughout the full Brillouin zone is still not possible due to the lack of available experimental tools. In this work, phonon dispersion and chirality of tungsten carbide were investigated by millielectronvolt energy-resolution inelastic X-ray scattering. The atomistic calculation indicates that in-plane longitudinal and transverse acoustic phonons near K and K$^\prime$ points are circularly polarized due to the broken inversion symmetry. Anomalous inelastic X-ray scattering by these circularly polarized phonons was observed and attributed to their chirality. Our results show that inelastic X-ray scattering can be utilized to characterize phonon chirality in materials and suggest that a revision to the phonon scattering function is necessary.