A concept for the extraction of the most refractory elements at CERN-ISOLDE as carbonyl complex ions

TL;DR

This paper proposes a new thick-target method for extracting refractory transition metal radionuclides as volatile carbonyl complexes, enabling their use in radioactive ion beam production at ISOL facilities.

Contribution

It introduces a novel recoil-based extraction concept using carbonyl complex formation, overcoming diffusion limitations in traditional thick-target methods.

Findings

Validated the concept through parameter studies.

Demonstrated potential to extract molybdenum, tungsten, and other metals.

Outlined setup parameters for future implementation.

Abstract

We introduce a novel thick-target concept tailored to the extraction of refractory 4d and 5d transition metal radionuclides of molybdenum, technetium, ruthenium and tungsten for radioactive ion beam production. Despite the more than 60-year old history of thick-target ISOL mass-separation facilities like ISOLDE, the extraction of the most refractory elements as radioactive ion beam has so far not been successful. In ordinary thick ISOL targets, their radioisotopes produced in the target are stopped within the condensed target material and have to diffuse through a solid material. Here, we present a concept which overcomes limitations associated with this method. We exploit the recoil momentum of nuclear reaction products for their release from the solid target material. They are thermalized in a carbon monoxide-containing atmosphere, in which volatile carbonyl complexes form readily at ambient temperature and pressure. This compound serves as volatile carrier for transport to the ion source. Excess carbon monoxide is removed by cryogenic gas separation to enable low pressures in the source region, in which the species are ionized and hence made available for radioactive ion beam formation. The setup is operated in batch mode, with the aim to extract isotopes having half-lives of at least several seconds. We report parameter studies of the key processes of the method, which validate this concept and which define the parameters for the setup. This would allow for the first time the extraction of radioactive molybdenum, tungsten and several other transition metals at thick-target ISOL facilities.