Molecular Dynamics Modeling of Epoxy Resins using the Reactive Interface Force Field

TL;DR

This study uses the Reactive Interface Force Field (IFF-R) in molecular dynamics simulations to accurately predict thermo-mechanical properties of epoxy resins, validated against experimental data, aiding polymer design.

Contribution

First application of IFF-R to amorphous polymer systems, demonstrating its accuracy in predicting epoxy resin properties.

Findings

IFF-R predicts thermo-mechanical properties closely matching experiments.

The force field is reliable for molecular-level polymer property prediction.

Supports future design of composite materials and processing methods.

Abstract

Predictive computational modeling of polymer materials is necessary for the efficient design of composite materials and the corresponding processing methods. Molecular dynamics (MD) modeling is especially important for establishing accurate processing-structure-property relationships for neat resins. For MD modeling of amorphous polymer materials, an accurate force field is fundamental to reliable prediction of properties. Reactive force fields, in which chemical bonds can be formed or broken, offer further capability in predicting the mechanical behavior of amorphous polymers subjected to relatively large deformations. To this end, the Reactive Interface Force Field (IFF-R) has been recently developed to provide an efficient means to predict the behavior of materials under these conditions. Although IFF-R has been proven to be accurate for some crystalline organic and inorganic systems, it has not yet been proven to be accurate for amorphous polymer systems. The objective of this study is to use IFF-R to predict the thermo-mechanical properties of three different epoxy systems and validate with experimental measurements. The results indicate that IFF-R predicts thermo-mechanical properties that agree closely with experiment. Therefore, IFF-R can be used to reliably establish mechanical properties of polymers on the molecular level for future design of new composite materials and processing methods.