Anomalous Nernst thermopower and giant magnetostriction in microwave synthesized La0.5Sr0.5CoO3

TL;DR

This study reports on microwave-synthesized La0.5Sr0.5CoO3 exhibiting significant anomalous Nernst thermopower and giant magnetostriction, highlighting its potential for thermal energy harvesting and low-temperature actuation.

Contribution

It is the first to demonstrate the coexistence of anomalous Nernst thermopower and giant magnetostriction in La0.5Sr0.5CoO3 synthesized via microwave irradiation.

Findings

Anomalous Nernst thermopower reaches ~0.21 μV/K at 180 K.

Magnetostriction reaches 500 ppm at 40 K and below.

Sample exhibits ferromagnetism with T_C = 247 K.

Abstract

Ferromagnetic metallic oxides have potential applications in spincaloric devices which utilize the spin property of charge carriers for interconversion of heat and electricity through the spin Seebeck or the anomalous Nernst effect or both. In this work, we synthesized polycrystalline La0.5S0.5CoO3 by microwave irradiation method and studied its transverse thermoelectric voltage (Nernst thermopower) and change in the linear dimension of the sample (Joule magnetostriction) in response to external magnetic fields. In addition, magnetization, temperature dependences of electrical resistivity, and longitudinal Seebeck coefficient (Sxx) in absence of an external magnetic field were also measured. The sample is ferromagnetic with a Curie temperature of TC = 247 K and shows a metal-like resistivity above and below TC with a negative sign of Sxx suggesting charge transport due to electrons. Magnetic field dependence of the Nernst thermopower (Sxy) at a fixed temperature shows a rapid increase at low fields and a tendency to saturate at high fields as like the magnetization. Anomalous contribution to Sxy was extracted from total Sxy measured and it exhibits a maximum value of ~ 0.21 microV/K at 180 K for H = 50 kOe, which is comparable to the value found in a single crystal for a lower Sr content. The Joule magnetostriction is positive, i.e., the length of the sample expands along the direction of the magnetic field and it does not saturate even at 50 kOe. The magnetostriction increases with decreasing temperature below TC and reaches a maximum value of 500 ppm at T = 40 K and below. Coexistence of the anomalous Nernst thermopower and giant magnetostriction in a single compound has potential applications for thermal energy harvesting and low-temperature actuators, respectively.