Controlled Nucleation and Growth of Carbon Nitride Films on CNT Fiber Fabric for Photoelectrochemical Applications

TL;DR

This paper presents a method for controlled growth of carbon nitride films on carbon nanotube fabrics, enhancing their electronic properties and surface area for improved photoelectrochemical performance.

Contribution

It introduces a novel approach for growing CN films on CNT fibers using calcination and chemical vapor deposition, enabling tailored properties and efficient charge transfer.

Findings

CNTs act as nucleation centers for CN film growth

Enhanced charge transfer upon illumination

Increased electrochemical surface area

Abstract

The controlled growth of carbon nitride (CN) films with tailored electronic properties and surface area is quite challenging due to the solid-state reaction and the lack of efficient interaction between C-N monomers and substrates. Herein, controlled growth of CN films over robust carbon nanotubes (CNT) fiber fabric is reported, which is obtained by either direct calcination of melamine on their surface, that yields a bulk material, or by its chemical vapor deposition resulting in hybrid films. These materials are effective electrodes consisting of high surface-area CN containing CNT fiber fabrics acting as a scaffold and a highly conducting built-in current collector. The results confirm that CNTs act as nucleation centers for the formation of CN films, forming close contact at the CN/CNT interphase, and resulting in efficient charge transfer upon illumination and enhanced electrochemical surface area.