Evidence of nickel ions dimerization in NiWO$_4$ and NiWO$_4$-ZnWO$_4$ solid solutions probed by EXAFS spectroscopy and reverse Monte Carlo simulations

TL;DR

This study reveals the presence of magnetic Ni$^{2+}$ ion dimers in NiWO$_4$ and related solid solutions using EXAFS spectroscopy and RMC simulations, showing temperature and composition-dependent local structural changes.

Contribution

It provides the first detailed structural evidence of Ni$^{2+}$ dimerization in NiWO$_4$ and its solid solutions through combined EXAFS and RMC analysis.

Findings

Ni$^{2+}$ ions form dimers in NiWO$_4$ across all temperatures studied.

Dimerization persists in solid solutions with Ni content up to 60%.

Radial distribution functions reveal detailed local environment changes.

Abstract

The existence of exchange-coupled Ni$^{2+}$ ions -- the so-called magnetic dimers -- in wolframite-type NiWO$_4$ and Zn$_c$Ni$_{1-c}$WO$_4$ solid solutions with high nickel content was discovered by X-ray absorption spectroscopy combined with reverse Monte Carlo (RMC) simulations. Temperature- (10--300 K) and composition-dependent x-ray absorption spectra were measured at the Ni K-edge, Zn K-edge, and W L$_3$-edge of microcrystalline NiWO$_4$, Zn$_c$Ni$_{1-c}$WO$_4$ and ZnWO$_4$. Structural models were obtained from simultaneous analysis of the extended x-ray absorption fine structure (EXAFS) spectra at three metal absorption edges using RMC simulations. The obtained radial distribution functions for different atomic pairs made it possible to trace in detail the changes in the local environment of metal ions and the effect of thermal disorder. Dimerization of Ni$^{2+}$ ions within quasi-one-dimensional zigzag chains of [NiO$_6$] octahedra was evidenced in NiWO$_4$ in the whole studied temperature range. It manifests itself as the splitting of the Ni-Ni radial distribution function into two separate peaks. The effect is further preserved in solid solutions Zn$_c$Ni$_{1-c}$WO$_4$ for $c \leq 0.6$, which is related to the probability to find two Ni$^{2+}$ ions in neighboring positions.