Resonantly pumped bright-triplet exciton lasing in caesium lead bromide perovskites

TL;DR

This paper demonstrates a resonant pumping scheme in CsPbBr3 nanocrystals that produces a bright, polarized triplet-laser source with enhanced coherence and spectral purity, advancing perovskite-based nano-laser technology.

Contribution

It introduces a novel resonant optical pumping method targeting triplet states in lead halide perovskite nanocrystals, significantly improving laser emission characteristics.

Findings

Enhanced coherent emission by one order of magnitude

Achieved polarized, high-contrast triplet lasing

Resolved exciton fine-structure through polarization and spectroscopy

Abstract

The surprising recent observation of highly emissive triplet-states in lead halide perovskites accounts for their orders-of-magnitude brighter optical signals and high quantum efficiencies compared to other semiconductors. This makes them attractive for future optoelectronic applications, especially in bright low-threshold nano-lasers. Whilst non-resonantly pumped lasing from all-inorganic lead-halide perovskites is now well-established as an attractive pathway to scalable low-power laser sources for nano-optoelectronics, here we showcase a resonant optical pumping scheme on a fast triplet-state in CsPbBr3 nanocrystals. The scheme allows us to realize a polarized triplet-laser source that dramatically enhances the coherent signal by one order of magnitude whilst suppressing non-coherent contributions. The result is a source with highly attractive technological characteristics including a bright and polarized signal, and a high stimulated-to-spontaneous emission signal contrast that can be filtered to enhance spectral purity. The emission is generated by pumping selectively on a weakly-confined excitonic state with a Bohr radius ~10 nm in the nanocrystals. The exciton fine-structure is revealed by the energy-splitting resulting from confinement in nanocrystals with tetragonal symmetry. We use a linear polarizer to resolve two-fold non-degenerate sub-levels in the triplet exciton and use photoluminescence excitation spectroscopy to determine the energy of the state before pumping it resonantly.