Alloying driven transition between ferro- and antiferromagnetism in UTGe compounds: the UCo1-xIrxGe case

TL;DR

This study investigates how alloying UCoGe with Ir affects its magnetic phases, revealing a transition from ferromagnetism to antiferromagnetism and the emergence of a correlated paramagnetic phase, with detailed phase diagram mapping.

Contribution

It provides the first detailed phase diagram of UCo1-xIrxGe showing the suppression of ferromagnetism and antiferromagnetism and the dominance of a correlated paramagnetic phase with increasing Ir content.

Findings

Ferromagnetism and superconductivity vanish at x=0.02

Antiferromagnetism decreases and vanishes near x=0.8

A correlated paramagnetic phase dominates between 0.02 and 0.8

Abstract

The evolution of magnetic properties of isostructural and isoelectronic solid solutions of the superconducting itinerant 5f-electron ferromagnet UCoGe with antiferromagnet UIrGe was studied by magnetization, AC susceptibility, specific heat, and electrical resistivity measurements of a series of UCo1-xIrxGe compounds in polycrystalline and single crystalline form at various temperatures and magnetic fields. Both the weak ferromagnetism and superconductivity in UCoGe were found to have vanished already for very low Ir substitution for Co x = 0.02. The antiferromagnetism of UIrGe is gradually suppressed. This is documented by a rapid decrease in both Neel temperature and the critical field of the metamagnetic transition with decreasing Ir concentration, which both tend to vanish just above x = 0.8. The section of the T-x phase diagram in the range x between 0.02 and 0.8 is dominated by a correlated paramagnetic phase exhibiting very broad bumps in temperature dependencies of b-axis magnetization and specific heat developing with increasing x. For x = 0.24, wide peaks appear in the c-axis thermomagnetic curves due to antiferromagnetic correlations which may eventually lead to frozen incoherent spin configurations at low temperatures. The correlated paramagnetic phase is also accompanied by specific electrical resistivity anomalies. The T-x phase diagram determined for the UCo1-xIrxGe compounds contrasts with the behavior of the related URh1-xIrxGe system, which was reported to exhibit an extended concentration range of stable ferromagnetism in Rh rich compounds and a discontinuous transformation between the ferromagnetic and antiferromagnetic phases at a critical Rh-Ir concentration.