Direct microscopic evidence of shear induced graphitization of ultrananocrystalline diamond films

TL;DR

This study provides microscopic evidence of shear-induced graphitization in ultrananocrystalline diamond films, revealing how different growth atmospheres influence tribofilm structure, wear resistance, and friction properties.

Contribution

It demonstrates direct micro- and nanoscopic evidence of shear-induced graphitization and its role in ultralow friction and wear in UNCD films with different growth conditions.

Findings

UNCDAr films show higher wear resistance than UNCDN.

Shear-induced graphitization leads to formation of graphene networks.

Large graphene networks correlate with ultralow friction and wear.

Abstract

The origin of ultralow friction and high wear resistance in ultrananocrystalline diamond (UNCD) films is still under active debate because of the perplexed tribochemistry at the sliding interface. Herein, we report a comparative study on surface topography and nanoscale friction of tribofilms, in wear tracks of two sets of UNCD films having different structural characteristics. Despite both the films display ultralow coefficient of friction, the UNCD films grown under Ar atmosphere (UNCDAr) exhibit a high wear resistance while the wear rate is higher for the films grown in N2 (UNCDN). Frictional force microscopic (FFM) investigations clearly reveal the manifestation of shear induced graphitization on both the films. However, the wear track of UNCDAr films have a large network of a few layer graphene (FLG) structures over the amorphous carbon tribofilms while only isolated clusters of FLG structures are present in the wear track of UNCDN films. Here, we demonstrate the direct micro-/nanoscopic evidence for the formation of large network of ~ 0.8 - 6 nm thick FLG structures, as a consequence of shear induced graphitization and discuss their decisive role in ultralow friction and wear.