Yield stress and other flow and wall slip parameters of viscoplastic fluids from steady torsional flow

TL;DR

This paper presents a method to determine the yield stress and other flow parameters of viscoplastic fluids from steady torsional flow data, overcoming wall slip issues without damaging the sample.

Contribution

It introduces a novel approach to extract yield stress and shear viscosity parameters from torque versus shear rate data using a single gap in steady torsional flow.

Findings

Yield stress can be identified from slope changes in torque-shear rate data.

The method is validated by comparing wall slip velocities with wall velocities.

Parameters of shear viscosity and wall slip behavior are successfully determined.

Abstract

The ubiquitous wall slip behavior of viscoplastic fluids renders the analysis of their steady torsional flow data to determine their yield stress and other parameters of their shear viscosity material function challenging. Roughened surfaces to prevent wall slip can be used but such methods frequently result in the fracturing of the sample. Instead, it is shown here that the yield stress of a viscoplastic fluid can be determined from the torque versus apparent shear rate data of steady torsional flow using a single gap. The step change in the slope of the torque versus apparent shear rate data of a viscoplastic fluid marks the yield stress of the fluid. For demonstration, the earlier-characterized parameters of the shear viscosity and apparent wall slip behavior of a viscoplastic suspension [He et al., J. Rheology, 63, 19 (2019)] were used for obtaining the shear stress distribution and the torque at each rotational speed. The yield stress, determined from the torque versus apparent shear rate data, could be verified by using a second method relying on the comparison of the wall slip velocities with wall velocities, while at the same time enabling the determination of the other parameters of the shear viscosity material function of the viscoplastic fluid.