On the Role of Atomic Binding Forces and Warm-Dense-Matter Physics in the Modeling of mJ-Class Laser-Induced Surface Ablation

TL;DR

This paper models laser-induced surface ablation in warm-dense-matter regimes, emphasizing atomic binding forces and advanced equations of state, and validates the approach with hydrodynamic simulations matching experimental data.

Contribution

It introduces a comprehensive hydrodynamic model incorporating advanced EOS and binding pressure calculations to better understand and predict laser ablation in warm-dense-matter conditions.

Findings

A fully nonlinear hydrodynamic simulation matches experimental ablation depths.

Re-condensation effects significantly reduce ablation depth at certain fluences.

A transition from electrostatic to pressure-driven ablation occurs with increasing laser fluence.

Abstract

Ultrafast laser heating of electrons on a metal surface breaks the pressure equilibrium within the material, thus initiating ablation. The stasis of a room-temperature metal results from a balance between repulsive and attractive binding pressures. We calculate this with a choice of Equation of State (EOS), whose applicability in the Warm-Dense-Matter regime is varied. Hydrodynamic modeling of surface ablation in this regime involves calculation of electrostatic and thermal forces implied by the EOS, and therefore the physics outlining the evolution of the net inter-atomic binding (negative pressure) during rapid heating is of interest. In particular, we discuss the Thomas-Fermi-Dirac-Weizsacker model, and Averaged Atom Model, and their binding pressure as compared to the more commonly used models. A fully nonlinear hydrodynamic code with a pressure-sourced electrostatic field solver is then implemented to simulate the ablation process, and the ablation depths are compared with known measurements with good agreement. Results also show that re-condensation of a previously melted layer significantly reduces the overall ablated depth of copper for laser fluence between 10-30J/cm^2, further explaining a well-known trend observed in experiments in this regime. A transition from electrostatic to pressure-driven ablation is observed with laser fluence increasing.