Competing magnetic interactions and magnetocaloric effect in Ho$_5$Sn$_3$

TL;DR

This study investigates the complex magnetic behavior and magnetocaloric effect in Ho$_5$Sn$_3$, revealing multiple magnetic transitions, field-driven metamagnetism, and a sign change in entropy change linked to spin reorientations, supported by experimental and theoretical analyses.

Contribution

It provides a comprehensive experimental and theoretical analysis of Ho$_5$Sn$_3$, highlighting its multiple magnetic transitions, magnetocaloric properties, and the influence of Coulomb interactions on its magnetic ground state.

Findings

Ho$_5$Sn$_3$ orders antiferromagnetically below 28 K.

Significant magnetocaloric effect with entropy change up to -9.5 JKg$^{-1}$K$^{-1}$ at 30 K.

Presence of multiple spin reorientation transitions affecting magnetic entropy.

Abstract

The rare-earth intermetallic compound Ho$_5$Sn$_3$ demonstrates fascinating magnetic properties which include temperature-driven multiple magnetic transitions and field driven metamagnetism. We address the magnetic character of this exciting compound through a combined experimental and theoretical studies. Ho$_5$Sn$_3$ orders antiferromagnetically below $~28$ K, and shows further spin reorientation transitions at 15 K and 12 K. We observe a sizable amount of low-temperature magnetocaloric effect in Ho$_5$Sn$_3$ with a maximum value of entropy change $\Delta S$ = -9.5 JKg$^{-1}$K$^{-1}$ for an applied field of $H$ = 50 kOe at around 30 K. The field hysteresis is almost zero above 15 K where magneto-caloric effect is important. Interestingly, $\Delta S$ is found to change its sign from positive to negative as the temperature is increased above about 8 K, which can be linked to the multiple spin reorientation transitions. The signature of the metamagnetism is visible in the $\Delta S$ versus $H$ plot. The magnetic ground-state, obtained from the density functional theory based calculation, is susceptible to the effective Coulomb interaction ($U_{\rm eff}$) between electrons. Depending upon the value of $U_{\rm eff}$, the ground-state can be ferromagnetic or antiferromagnetic. The compound shows large relaxation (14\% change in magnetization in 60 min) in the field cooled state with a logarithmic time variation, which may be connected to the competing magnetic ground-states observed in our theoretical calculations. The competing magnetic ground-states is also evident from the small value of the paramagnetic Curie-Weiss temperature.