Na Site Doping a Pathway for Enhanced Thermoelectric Performance in $Na_{1-x}CoO_2$; The Case of Gd and Yb Dopants

TL;DR

This study investigates how Gd and Yb dopants occupy different lattice sites in Na$_{1-x}$CoO$_2$ depending on the environment, affecting thermoelectric properties and guiding doping strategies for performance enhancement.

Contribution

It reveals the site-specific behavior of Gd and Yb dopants in Na$_{1-x}$CoO$_2$ and how synthesis conditions influence thermoelectric improvements.

Findings

Gd and Yb prefer Na sites in oxygen-poor environments.

Doping at Na sites increases the power factor in Na$_{0.50}$CoO$_2$.

Dopants replacing Co decrease thermoelectric performance.

Abstract

Doping is considered to be the main method for improving the thermoelectric performance of layered sodium cobaltate (Na$_{1-x}$CoO$_2$). However, in the vast majority of past reports, the equilibrium location of the dopant in the Na$_{1-x}$CoO$_2$'s complex layered lattice has not been confidently identified. Consequently, a universal strategy for choosing a suitable dopant for enhancing Na$_{1-x}$CoO$_2$'s figure of merit is yet to be established. Here, by examining the formation energy of Gd and Yb dopants in Na$_{0.75}$CoO$_2$ and Na$_{0.50}$CoO$_2$, we demonstrate that in an oxygen poor environment, Gd and Yb dopants reside in the Na layer while in an oxygen rich environment these dopants replace a Co in CoO$_2$ layer. When at Na layer, Gd and Yb dopants reduce the carrier concentration via electron-hole recombination, simultaneously increasing the Seebeck coefficient ($S$) and reducing electric conductivity ($\sigma$). Na site doping, however, improves the thermoelectric power factor (PF) only in Na$_{0.50}$CoO$_2$. When replacing a Co, these dopants reduce $S$ and PF. The results demonstrate how thermoelectric performance critically depends on the synthesis environment that must be fine-tuned for achieving any thermoelectric enhancement.