Spin dynamics of itinerant electrons: local magnetic moment formation and Berry phase

TL;DR

This paper develops a theoretical framework for understanding spin dynamics in itinerant electrons, establishing the existence of local magnetic moments in the paramagnetic regime and deriving their Berry phase, with implications for magnetic material modeling.

Contribution

It introduces a method to describe local magnetic moments and their dynamics directly from a fermionic model, even above magnetic transition temperatures, and derives the Berry phase associated with spin fluctuations.

Findings

Local magnetic moments can form above magnetic ordering temperatures.

The Berry phase for spin dynamics is explicitly derived from electronic models.

The Landau-Lifshitz equation with Gilbert damping describes large magnetic moments.

Abstract

The state-of-the-art theoretical description of magnetic materials relies on solving effective Heisenberg spin problems or their generalizations to relativistic or multi-spin-interaction cases that explicitly assume the presence of local magnetic moments in the system. We start with a general interacting fermionic model that is often obtained in ab initio electronic structure calculations and show that the corresponding spin problem can be introduced even in the paramagnetic regime, which is characterized by a zero average value of the magnetization. Further, we derive a physical criterion for the formation of the local magnetic moment and confirm that the latter exists already at high temperatures well above the transition to the ordered magnetic state. The use of path-integral techniques allows us to disentangle spin and electronic degrees of freedom and to carefully separate rotational dynamics of the local magnetic moment from Higgs fluctuations of its absolute value. It also allows us to accurately derive the topological Berry phase and relate it to a physical bosonic variable that describes dynamics of the spin degrees of freedom. As the result, we demonstrate that the equation of motion in the case of a large magnetic moment takes a conventional Landau-Lifshitz form that explicitly accounts for the Gilbert damping due to itinerant nature of the original electronic model.