Magnetic transitions in the 1-D chain compounds NdPd5Ge3 and NdPt5Ge3

TL;DR

This study reports the discovery and initial magnetic characterization of two new 1D Nd chain compounds, revealing their magnetic ordering and field-induced transitions, with implications for understanding low-dimensional magnetic systems.

Contribution

It introduces two previously unreported Nd-based chain compounds with detailed structural and magnetic characterization, highlighting their magnetic transitions and field effects.

Findings

NdPd5Ge3 orders magnetically at ~2.2 K

NdPt5Ge3 orders magnetically at ~3.0 K

NdPd5Ge3 exhibits a magnetic-field-induced transition below 2K

Abstract

We present the structural and initial magnetic characterization of the previously unreported materials NdPd5Ge3 and NdPd5Ge3. These materials, with 1-dimensional Nd chains, crystallize in the orthorhombic YNi5Si3-type structure in space group Pnma. Magnetic ordering is observed for both compounds at ~ 2.2 K for NdPd5Ge3 and ~ 3.0 K for NdPt5Ge3. A magnetic-field-induced transition is clearly observed for NdPd5Ge3 below 2K, at an applied magnetic field of around 1.6 Tesla. The heat capacity data reveals that essentially all the available magnetic entropy is released at the magnetic ordering transition for NdPd5Ge3 but that only 29% is seen for NdPt5Ge3 at temperatures down to 1.5 K, the data implying that a second magnetic transition can be expected at lower temperatures.