Two-photon exchange corrections to the $g$ factor of Li-like ions
V. A. Yerokhin, C. H. Keitel, and Z. Harman

TL;DR
This paper presents all-order QED calculations of two-photon exchange corrections to the $g$ factor of Li-like ions, improving theoretical accuracy and revealing discrepancies with experimental data for silicon and calcium.
Contribution
The study introduces a comprehensive all-orders QED approach to compute two-photon exchange corrections, enhancing precision over previous methods.
Findings
Improved theoretical $g$ factor predictions for Li-like carbon and oxygen.
Consistency among QED, relativistic many-body perturbation theory, and nonrelativistic QED methods.
Discrepancies between theory and experiment for silicon and calcium by 3-4 standard deviations.
Abstract
We report calculations of QED corrections to the factor of Li-like ions induced by the exchange of two virtual photons between the electrons. The calculations are performed within QED theory to all orders in the nuclear binding strength parameter , where is the nuclear charge number and is the fine-structure constant. In the region of low nuclear charges we compare results from three different methods: QED, relativistic many-body perturbation theory, and nonrelativistic QED. All three methods are shown to yield consistent results. With our calculations we improve the accuracy of the theoretical predictions of the factor of the ground state of Li-like carbon and oxygen by about an order of magnitude. Our theoretical results agree with those from previous calculations but differ by 3-4 standard deviations from the experimental results available for silicon…
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