Effects of a non-causal electromagnetic response on the linear momentum transfer from a swift electron to a metallic nanoparticle

TL;DR

This paper investigates how non-causal electromagnetic responses affect the linear momentum transfer from swift electrons to metallic nanoparticles, revealing that previous unphysical results are due to non-causality and that the transfer is always attractive.

Contribution

It demonstrates that non-causality in dielectric functions can lead to incorrect momentum transfer results, providing corrected insights with a numerical approach.

Findings

Non-causality can cause incorrect repulsive momentum transfer results.

Corrected results show always attractive momentum transfer for aluminum and gold nanoparticles.

Numerical convergence issues can affect the validity of theoretical predictions.

Abstract

Electron beams in Scanning Transmission Electron Microscopes (STEMs) can be used as a tool to induce movement on nanoparticles. Employing a classical-electrodynamics approach, it has been reported that the linear momentum transfer from a STEM-beam electron to a metallic spherical nanoparticle can be either repulsive or attractive towards the swift electron trajectory. This is in qualitative agreement with experimental observations. The interaction time between a swift electron and a nanoparticle is typically on the order of attoseconds. Hence, the electromagnetic response of the nanoparticle at short times is of utmost importance. However, it has been reported that the dielectric function employed in previous studies presented a non-causal pre-echo at the attosecond timescale, which might have lead to incorrect unphysical results. Therefore, the validity of these linear momentum transfer results should be revisited. In this theoretical work, we study the non-causality effects on the linear momentum transferred from a swift electron to a metallic nanoparticle, made of either aluminum or gold. Using an efficient numerical methodology, we found that non-causality, as well as deficient numerical convergence, may lead to incorrect repulsive linear momentum transfer results. Contrary to what previous theoretical studies have reported, our results show that the linear momentum transfer from a swift electron to spherical aluminum and gold nanoparticles, with radius 1 nm, is always attractive.