Observations and analysis of CH$^+$ vibrational emissions from the young, carbon-rich planetary nebula NGC 7027: a textbook example of chemical pumping
David A. Neufeld (JHU), Benjamin Godard (Obs. Paris), P. Bryan, Changala (CfA), Alexandre Faure (Grenoble), T. R. Geballe (Gemini), Rolf, G\"usten (MPIfR), Karl M. Menten (MPIfR), and Helmut Wiesemeyer (MPIfR)

TL;DR
This study reports the detection of multiple rovibrational lines of CH$^+$ and H$_2$ in the planetary nebula NGC 7027, demonstrating that chemical pumping predominantly excites CH$^+$, with a model accurately matching observed line fluxes.
Contribution
First detailed analysis of CH$^+$ vibrational emissions in NGC 7027 showing chemical pumping as the main excitation mechanism.
Findings
Chemical pumping dominates CH$^+$ excitation.
Model successfully reproduces line fluxes.
Detected multiple rovibrational lines of CH$^+$ and H$_2$.
Abstract
We discuss the detection of 14 rovibrational lines of CH, obtained with the iSHELL spectrograph on NASA's Infrared Telescope Facility (IRTF) on Maunakea. Our observations in the 3.49 - 4.13 m spectral region, obtained with a 0.375" slit width that provided a spectral resolving power , have resulted in the unequivocal detection of the and transitions within the band of CH. The -branch transitions are anomalously weak relative to the -branch transitions, a behavior that is explained accurately by rovibronic calculations of the transition dipole moment reported in a companion paper (Changala et al. 2021). Nine infrared transitions of H were also detected in these observations, comprising the , , and pure rotational lines; the lines, and the …
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