Operando probing of Li-insertion into LiMn$_2$O$_4$ cathodes by spectroscopic ellipsometry

TL;DR

This paper introduces a non-destructive spectroscopic ellipsometry method for real-time observation of lithium intercalation in battery cathodes, enabling insights into ion diffusion and electrochemical behavior.

Contribution

It presents a novel operando spectroscopic ellipsometry technique for studying ion intercalation in battery electrodes, specifically applied to LiMn₂O₄ cathodes, revealing diffusion properties and nanostructure effects.

Findings

Determined Li+ diffusivity in LiMn₂O₄ using SE.

Linked pseudo-capacitive behavior to nanostructure.

Established SE as a tool for operando battery analysis.

Abstract

A novel non-destructive methodology for operando observation of ion intercalation and the state of charge on battery electrodes is presented based on spectroscopic ellipsometry (SE). The potentiality of this technique for performing time-resolved measurements of (de-)lithiation processes on electrode materials has been demonstrated using thin film spinel LiMn$_2$O$_4$ as a cathode for Li-ion batteries. The chemical diffusivity of Li+ ions in this material has been determined by the time evolution of the Li insertion into the film, and in the light of these results, it has been possible to relate the controversial pseudo-capacitive behavior observed in this material to the nanostructure of the layer. The results presented here establish a new way for operando characterization of battery materials and devices providing a powerful tool for the understanding of ion diffusion mechanisms in a collection of electrochemical devices.