A decatungstate-based Ionic liquid exhibiting very low dielectric constant suitable for acting as solvent and catalyst for oxidation of organic substrates
Yohan Martinetto (ILV), Bruce P\'egot (ILV), Catherine Roch (ILV),, Mohamed Haouas (ILV), Betty Cottyn (IJPB), Franck Camerel (ISCR), Jelena, Jeftic (ISCR), Denis Morineau (IPR), Emmanuel Magnier (ILV), S\'ebastien, Floquet (ILV)
TL;DR
This paper introduces a novel POM-based ionic liquid with a very low dielectric constant, suitable as both solvent and catalyst for oxidation reactions, demonstrated through catalytic oxidation of alcohols and alkenes.
Contribution
It presents a new ionic liquid with combined solvent and catalytic properties, characterized by low viscosity and dielectric constant for organic oxidation processes.
Findings
Effective oxidation of alcohols and alkenes demonstrated
Unique ionic liquid acts as both solvent and catalyst
Low dielectric constant enhances oxidation efficiency
Abstract
In this contribution, a new POM-based ionic liquid, namely (P6,6,6,14)4[W10O32], was fully characterized. Its viscosity and its very low dielectric constant make this hybrid ionic liquid suitable to be used as solvent for organic transformations. As proof of concept, this unique ionic liquid combining solvant and catalyst properties was tested for catalytic oxidation of various alcohols and alkenes in presence of H2O2
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