Atomic Transition Probabilities of Neutral Calcium

TL;DR

This study evaluates modern theoretical transition probabilities for neutral calcium against experimental data, producing an accurate line list and refining calcium abundance measurements in the Sun and a metal-poor star.

Contribution

It provides a comprehensive comparison of ab initio calculations with experimental data and delivers an improved, validated line list of Ca I transition probabilities.

Findings

Modern theory generally agrees with experimental data

A final list of 202 recommended transition probabilities is presented

Refined calcium abundance measurements in the Sun and HD 84937

Abstract

The goals of this study are 1) to test the best theoretical transition probabilities for Ca I (a relatively light alkaline earth spectrum) from a modern ab initio calculation using configuration interaction plus many body perturbation theory against the best modern experimental transition probabilities, and 2) to produce as accurate and comprehensive a line list of Ca I transition probabilities as is currently possible based on this comparison. We report new Ca I radiative lifetime measurements from a laser-induced fluorescence (LIF) experiment and new emission branching fraction measurements from a 0.5 m focal length grating spectrometer with a detector array. We combine these data for upper levels that have both a new lifetime and new branching fractions to report log(gf)s for two multiplets consisting of nine transitions. Detailed comparisons are made between theory and experiment, including the measurements reported herein and a selected set of previously published experimental transition probabilities. We find that modern theory compares favorably to experimental measurements in most instances where such data exist. A final list of 202 recommended transition probabilities is presented, which covers lines of Ca I with wavelengths ranging from 2200 - 10,000 Angstroms. These are mostly selected from theory, but are augmented with high quality experimental measurements from this work and from the literature. The recommended transition probabilities are used in a redetermination of the Ca abundance in the Sun and in the metal-poor star HD 84937.