Long-range atom-ion Rydberg molecule: A novel molecular binding mechanism

TL;DR

This paper introduces a new type of long-range molecule formed by a Rydberg atom and an ion, based on electric field-induced level crossings, with potential applications in quantum dynamics studies.

Contribution

It proposes a novel binding mechanism for atom-ion Rydberg molecules and characterizes their properties, including lifetime, structure, and detection methods.

Findings

Potential wells enable molecule formation at specific distances

Large dipole moments and vibrational structures identified

Methods for production and detection discussed

Abstract

We present a novel binding mechanism where a neutral Rydberg atom and an atomic ion form a molecular bound state at large internuclear distance. The binding mechanism is based on Stark shifts and level crossings which are induced in the Rydberg atom due to the electric field of the ion. At particular internuclear distances between Rydberg atom and ion, potential wells occur which can hold atom-ion molecular bound states. Apart from the binding mechanism we describe important properties of the long-range atom-ion Rydberg molecule, such as its lifetime and decay paths, its vibrational and rotational structure, and its large dipole moment. Furthermore, we discuss methods how to produce and detect it. The unusual properties of the long-range atom-ion Rydberg molecule give rise to interesting prospects for studies of wave packet dynamics in engineered potential energy landscapes.